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Brother, TN-433 Black High Yield Toner Cartridge, TN433BK-05/28/2021
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Printer tonerStructure such as solid, liquid, aerosol etc.
Form: powderDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 2024200 Crossing Boulevard
Bridgewater NJ 08807
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)2-Propenoic acid, butyl ester, polymer with ethenylbenzene 025767-47-9 65.0-75.0 No Fatty acid esters 999999-90-2 8.0-18.0 No Carbon black 001333-86-4 4.0-14.0 Yes 
CoC List
Styrene acrylic resin 025036-16-2 <7 No Polyalkylmethacrylate 009011-14-7 1.0-5.0 Yes CoC List
Fumed silica, crystalline-free 112945-52-5 <3 No Silica, amorphous (Diatomaceous silica) 007631-86-9 <3 No Fumed silica-Silicon dioxide (amorphous) 844491-94-7 <3 No Zinc stearate 000557-05-1 <0.2 Yes CoC List
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :May 28, 2021 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING0 0 0 -
Warnings
Hazard StatementsThe product contains no substances which at their given concentration, are considered to be hazardous to health.Precautionary StatementsGeneralNone.
PreventionNone.ResponseNone.StorageNone.DisposalNone. -
Acute health effects
From SDS:Hazards IdentificationEmergency OverviewNone.Potential Health EffectsEye Contact: May cause eye irritation.Skin Contact: : Repeated and/or prolonged skin contact may cause irritation.Ingestion: May cause stomach ache. Unlikely route of exposure.Inhalation: For large quantities: May cause irritation to the respiratory system. Increased difficulty in breathing. Sneezing. Coughing. -
Chronic health effects
From SDS:
No information. -
Carcinogenicity
Carbon Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This classification is given to chemicals, for which there is inadequate human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other than rats did not show any association between carbon black and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation containing carbon black demonstrated no association between toner exposure and tumor development in rats.Other ingredients of this product have not been classified as carcinogens according to IARC monographs, NTP and OSHA. -
Handling information
Keep out of the reach of children. Avoid generation of dust. Avoid inhalation of high concentrations of dust. Avoid contact with eyes. Keep out of the reach of children. Keep cool. Protect from sunlight. -
Disposal information
Do not put toner or toner cartridges into a fire, this can cause fire to spread with the risk of causing burn injuries. Shred toner cartridges in a dust/explosion controlled environment. Finely dispersed particles may form explosive mixtures in the air. Dispose of in accordance with Federal, State, and local regulations. This product contains one or more substances that are listed with the State of California as a hazardous waste. -
First Aid
Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.Skin Contact: Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician.Inhalation: Remove to fresh air. Get immediate medical advice/attention.Ingestion: Rinse mouth thoroughly with water. Get immediate medical advice/attention
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UN Global Harmonization Classification